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The kg is defined as being equal to the mass of the International Prototype of the Kilogram (IPK), a block of platinum-iridium alloy manufactured in 1889 and stored at the International Bureau of Weights and Measures in Sèvres, France.
It is the only SI unit that is defined by a physical object rather than a fundamental physical property that can be reproduced in laboratories.
The pound is a measurement of mass used in the imperial system, and is accepted on a day-to-day basis as a unit of weight (the gravitational force acting on any given object).